2. Black Widow
Despite having a less than ideal, shoehorned introduction and being the ONE Avenger without a solo film (because who cares about Hawkeye), Black Widow has still become one of the most compelling figures in the MCU. Lethal, clever and a wonderfully sardonic foil to those around her as she drags around the baggage that is her past, a large part of her intrigue is in how little we still know about her. Civil War will be her fifth outing as the character, and she remains the enigma of the group as we’re never quite sure just what she’s going to do next.
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